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KMID : 1059519900340010098
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Journal of the Korean Chemical Society
1990 Volume.34 No. 1 p.98 ~ p.101
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Study on the Recovery and Determination of Scandium from Tin Slag
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Cha Ki-Won
Jeong Eui-Sik
Kim Kyung-Hwan
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Abstract
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A new spectrophotometric determination method of scandium in the tin slag solution has been investigated using methyl thymol blue as a colorimetric reagent. Scandium is recovered by the anion exchange resin, Amberlite IRA 400, using the mixture solution of ammonium sulfate and sulfuric acid and an eluent. The mole ratio of complex of scandium and MTB at pH 6 is 1 to 1 and the wave length of the maximum absorbance is 585 nm and the molar absorptivity at this wave length is 2.0 × 104 l·mol-1·cm-1. When tin slag solution is loaded into anion exchange resin and eluted, ions in the solution except scandium ion are eluted rapidly and scandium is eluted lately. So scandium is recovered easily.
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KEYWORD
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